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Galvanic Couples & Metal Corrosion Chart

Explore the 26-metal galvanic compatibility chart (ASTM G82), calculate galvanic corrosion risks, and discover Filame's manufacturing expertise in springs, stampings, and multi-metal assemblies.

Galvanic corrosion (also termed bimetallic corrosion) is defined as the accelerated degradation resulting from physical contact between two dissimilar metals or alloys in the presence of an electrically conductive electrolyte.

In any conductive solution, an electrochemical galvanic series ranks metals according to their dissolution potential. When coupled directly, an electric current flows between them, accelerating the dissolution of the less noble alloy (the anode) while cathodically protecting the more noble metal (the cathode).

The potential differential (|ΔV|) indicates the direction of attack, but not its absolute magnitude. Electrolyte conductivity, operating temperature, assembly geometry, and particularly the relative surface area ratio between components are decisive factors.

Essential Conditions for Galvanic Corrosion

For galvanic corrosion to occur, three cumulative conditions must be met:

  1. Dissimilar metals: An electrochemical potential differential creating an electromotive force.
  2. Conductive electrolyte: Moisture, salt fog, condensation, or operating fluids acting as an ionic path.
  3. Electrical continuity: Direct metallic contact allowing electronic charge transfer.

The Area Effect: Small Anode vs Large Cathode

For a given galvanic current between two metals, current density and dissolution rate on the less noble component increase dramatically when that anode has a small surface area:

  • Unfavorable case: A small anode (screw, rivet, spring) attached to a large cathode (stainless steel or copper plate) undergoes severe, accelerated perforation.
  • Favorable case: A large anode surrounding a small cathode (e.g., zinc-plated sheet with small stainless fastener) distributes dissolution across a broad area, remaining virtually harmless.
Galvanic Compatibility Matrix

Galvanic Couples Matrix Table (26 Metals & Alloys)

Electrochemical potential differences calculated in millivolts (|ΔV|) in an electrolyte of water + 2% NaCl vs Saturated Calomel Electrode (SCE). Click any cell to sync the CAD calculator and size your components.

Reference conditions: static water + 2% NaCl at ~20°C vs SCE (interpreted using ASTM G82 methodology)
Practically indifferent contact (|ΔV| ≤ 100 mV)
Metal B (row) is the corroded ANODE
Metal A (column) is the corroded ANODE
Metal B (Row) ↓ Metal A (Column) →
Platinum
Gold
Z6CN18-09 Passivated 18-10 Stainless
Silver
Mercury
N Nickel
UZ23N22 Arcap (CuNiZn)
U Pure Copper
UA10 Aluminum Bronze
UZ39Pb Free-cutting Brass
UE12 Tin Bronze
E Pure Tin
Pb Lead
AU4G Duralumin (2017A)
XC8 à 10 Mild Structural Steel
AS10G Cast Aluminum (AS10G)
A5 Pure Aluminum 99.5%
XC80 à 120 High-Carbon Spring Steel
AG4.5MC Duralinox (AlMg 5083)
Cd Cadmium Plating
Fe Pure ARMCO Iron
ASG Almasilium (6060 Al)
C Hard Chromium (active)
EZ25 Tin-Zinc Solder (75/25)
Z Zinc & Galvanized Steel
G Magnesium (AZ31)
Platinum
0 130 250 350 350 430 450 570 600 650 770 800 840 940 1000 1065 1090 1095 1100 1100 1105 1105 1200 1360 1400 1950
Gold
130 0 120 220 220 300 320 440 470 520 640 670 710 810 870 935 960 965 970 970 975 975 1070 1230 1270 1820
Passivated 18-10 Stainless Z6CN18-09
250 120 0 100 100 180 200 320 350 400 520 550 590 690 750 815 840 845 850 850 855 855 950 1110 1150 1700
Silver
350 220 100 0 0 80 100 220 250 300 420 450 490 590 650 715 740 745 750 750 755 755 850 1010 1050 1600
Mercury
350 220 100 0 0 80 100 220 250 300 420 450 490 590 650 715 740 745 750 750 755 755 850 1010 1050 1600
Nickel N
430 300 180 80 80 0 20 140 170 220 340 370 410 510 570 635 660 665 670 670 675 675 770 930 970 1520
Arcap (CuNiZn) UZ23N22
450 320 200 100 100 20 0 120 150 200 320 350 390 490 550 615 640 645 650 650 655 655 750 910 950 1500
Pure Copper U
570 440 320 220 220 140 120 0 30 80 200 230 270 370 430 495 520 525 530 530 535 535 630 790 830 1380
Aluminum Bronze UA10
600 470 350 250 250 170 150 30 0 50 170 200 240 340 400 465 490 495 500 500 505 505 600 760 800 1350
Free-cutting Brass UZ39Pb
650 520 400 300 300 220 200 80 50 0 120 150 190 290 350 415 440 445 450 450 455 455 550 710 750 1300
Tin Bronze UE12
770 640 520 420 420 340 320 200 170 120 0 30 70 170 230 295 320 325 330 330 335 335 430 590 630 1180
Pure Tin E
800 670 550 450 450 370 350 230 200 150 30 0 40 140 200 265 290 295 300 300 305 305 400 560 600 1150
Lead Pb
840 710 590 490 490 410 390 270 240 190 70 40 0 100 160 225 250 255 260 260 265 265 360 520 560 1110
Duralumin (2017A) AU4G
940 810 690 590 590 510 490 370 340 290 170 140 100 0 60 125 150 155 160 160 165 165 260 420 460 1010
Mild Structural Steel XC8 à 10
1000 870 750 650 650 570 550 430 400 350 230 200 160 60 0 65 90 95 100 100 105 105 200 360 400 950
Cast Aluminum (AS10G) AS10G
1065 935 815 715 715 635 615 495 465 415 295 265 225 125 65 0 25 30 35 35 40 40 135 295 335 885
Pure Aluminum 99.5% A5
1090 960 840 740 740 660 640 520 490 440 320 290 250 150 90 25 0 5 10 10 15 15 110 270 310 860
High-Carbon Spring Steel XC80 à 120
1095 965 845 745 745 665 645 525 495 445 325 295 255 155 95 30 5 0 5 5 10 10 105 265 305 855
Duralinox (AlMg 5083) AG4.5MC
1100 970 850 750 750 670 650 530 500 450 330 300 260 160 100 35 10 5 0 0 5 5 100 260 300 850
Cadmium Plating Cd
1100 970 850 750 750 670 650 530 500 450 330 300 260 160 100 35 10 5 0 0 5 5 100 260 300 850
Pure ARMCO Iron Fe
1105 975 855 755 755 675 655 535 505 455 335 305 265 165 105 40 15 10 5 5 0 0 95 255 295 845
Almasilium (6060 Al) ASG
1105 975 855 755 755 675 655 535 505 455 335 305 265 165 105 40 15 10 5 5 0 0 95 255 295 845
Hard Chromium (active) C
1200 1070 950 850 850 770 750 630 600 550 430 400 360 260 200 135 110 105 100 100 95 95 0 160 200 750
Tin-Zinc Solder (75/25) EZ25
1360 1230 1110 1010 1010 930 910 790 760 710 590 560 520 420 360 295 270 265 260 260 255 255 160 0 40 590
Zinc & Galvanized Steel Z
1400 1270 1150 1050 1050 970 950 830 800 750 630 600 560 460 400 335 310 305 300 300 295 295 200 40 0 550
Magnesium (AZ31) G
1950 1820 1700 1600 1600 1520 1500 1380 1350 1300 1180 1150 1110 1010 950 885 860 855 850 850 845 845 750 590 550 0
Platine vs Or |ΔV|: 130 mV
Click any cell to inspect this galvanic pair.
Galvanic Screening Calculator

Galvanic Compatibility & Corrosion Risk Calculator

Evaluate potential differential (|ΔV|), identify the sacrificial anode, and estimate galvanic driving force under reference conditions and geometric area ratios (Ac / Aa).

Preliminary Engineering Screening Note (ASTM G82 / ISO 8044 / DIN 50919:2022-02) : Preliminary screening based on open-circuit potential data in water + 2% NaCl vs SCE. Potential difference (ΔV) thresholds (≤150 mV marine, ≤250 mV industrial, ≤500 mV controlled) are legacy engineering screening heuristics and do not constitute MIL-STD-889D acceptance criteria. Actual galvanic corrosion depends on polarization kinetics, electrolyte conductivity, surface condition, and geometry. This screening does not substitute for environmental testing (ISO 9227) or application qualification.
1. Bimetallic Assembly Configuration
Cathodic to anodic area ratio (Ac / Aa): 1.0x
2. Electrochemical Diagnostic & Prescriptions
Status Diagnostic
Low ΔV — Low galvanic driving force (preliminary screening)
Potential Differential (|ΔV|) 40 mV
Screening margin
-110 mV ≤ 150 mV (OK)
ANODE (Less Noble / Dissolution) +80 mV
Spring Stainless Steel 1.4310 / AISI 301 (Passivated)
1.4310 / AISI 301 (EN 10270-3)
Oxidation: M → Mᶻ⁺ + z e⁻ (Dissolution)
CATHODE (More Noble / Protected) +120 mV
Marine Stainless 1.4404 / 316L (Passivated)
1.4404 / AISI 316L (EN 10088-3)
Reduction: O₂ + 2H₂O + 4e⁻ → 4OH⁻ (Protected)
Area ratio factor (Ac / Aa) : 1.0x 1 : 1

Under cathodic diffusion control, anodic current density scales approximately with the Ac / Aa area ratio. Polarization effects, electrolyte resistance, and localized corrosion (ASTM G102) can alter actual local damage.

Technical recommendations

Low potential separation (|ΔV| within legacy screening threshold). Application-specific evaluation recommended.

ISO 9001 • FABRICANT EUROPÉEN

Get a quote for your multi-metal assembly specifications

Submit your 2D / 3D STEP drawings and material requirements for technical feasibility review and quotation.

Filame Engineering

Filame's Expertise

How Filame integrates galvanic corrosion risk mitigation into tooling design, alloy selection, and serial manufacturing of springs and multi-metal stampings.

01 • Material Selection

Metallurgical Harmonization & Noble Alloys

Minimizing potential differences (|ΔV| ≤ 150 mV) through engineered material substitution.

Certified stamping and wire forming of stainless spring steels (1.4310 / 301, 1.4404 / 316L, 1.4568 / 17-7 PH) and nickel superalloys (Inconel 718, Inconel X-750) with complete EN 10204 3.1 mill traceability.
02 • Coatings & Treatments

High-Performance Barriers & De-Embrittlement

Neutralizing the galvanic cell via barrier coatings engineered for aggressive saline environments.

Zinc-Nickel plating (12–15% Ni per DIN 50979 / AMS 2417, up to >1,000h salt spray resistance), non-electrolytic zinc flake (Geomet / Dacromet per ISO 10683), and specification-compliant post-plating baking (ISO 24251-1 / AMS 2759/9) for high-tensile spring steel.
03 • Tooling Design

Dielectric Isolation & Multi-Metal Assembly

Eliminating electrical continuity between dissimilar metals within the mechanical joint.

Progressive die design integrating non-conductive washers/sleeves (PTFE, POM, PA66) and automated bi-metal joining on Bihler multi-slide machines and robotic riveting cells.
04 • Corrosion Kinetics

Geometric Surface Area Ratio Optimization

Systematic prevention of the high-risk 'small anode / large cathode' configuration.

Technical feasibility audit of client 3D STEP files and 2D blueprints by Filame's engineering office to optimize contact geometry, surface ratios, and electrolyte drainage.
Industrial Applications

Key Industries & Critical Bimetallic Couplings

Aerospace & Defense

Aerospace & Defense

Critical coupling: Carbon / Titanium / Aluminum

Carbon-fiber reinforced polymers (CFRP) and titanium fasteners form aggressive cathodic couples against 7075/2024 aluminum airframes. Filame manufactures certified precision springs and clips complying with EN 9100 quality demands.

Discover our expertise in this sector →
Automotive & E-Mobility

Automotive & E-Mobility

Critical coupling: Battery Packs & Steel / Aluminum Joints

Fastening aluminum battery housings with high-strength steel brackets under road-salt spray requires Zinc-Nickel (DIN 50979) or Geomet barrier coatings backed by systematic post-plating hydrogen de-embrittlement baking.

Discover our expertise in this sector →
Railway & Electrical Infrastructure

Railway & Electrical Infrastructure

Critical coupling: Copper Catenaries & Steel / Brass Mounts

Copper/bronze electrical contact clips mounted onto galvanized steel bogies or carriages endure severe cyclic fatigue in wet outdoor air. Filame provides precision multi-slide stampings and selective-plated spring contacts.

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Energy, Marine & Offshore

Energy, Marine & Offshore

Critical coupling: Saline Immersion & Stainless / Bronze Joints

In marine electrolytes (2–3.5% NaCl), the strict |ΔV| ≤ 150 mV design limit governs alloy selection. Filame forms high-grade corrosion-resistant metals including 316L stainless, Duplex 1.4462, and Inconel 718.

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Industrial Seals & Fluid Handling

Industrial Seals & Fluid Handling

Critical coupling: Inconel / Hastelloy Springs vs Steel Flanges & Graphite

Graphite gaskets and spring-energized PTFE seals trap conductive electrolytes within tight crevices. Filame manufactures continuous-length springs in noble superalloys (Inconel 718, Hastelloy C276, Elgiloy) to eliminate galvanic cells and maintain seal loading.

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Medical Devices & Surgical Instruments

Medical Devices & Surgical Instruments

Critical coupling: Titanium vs 1.4441 Stainless & Physiological Fluid

In physiological saline (0.9% NaCl at 37°C) and during autoclave steam cycles (134°C), galvanic couples are strictly prohibited to prevent toxic ion release (metallosis). Filame produces cleanroom-packaged springs in implant-grade 1.4441, 316LVM, and Elgiloy.

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Production capacities

Discover our manufacturing capabilities for springs and multi-metal stampings:

Questions & Answers

01 How does Filame's engineering team prevent galvanic corrosion in multi-metal assemblies ?
During the co-engineering phase with your 3D STEP files or 2D technical drawings, our metallurgical engineers evaluate the electrochemical potential difference (ΔV) between mating metals. We prescribe compatible alloy substitutions (such as Inconel or 316L stainless steel), high-performance barrier surface platings (Zinc-Nickel, chemical passivation EN 2516, Geomet), or dielectric isolation.
02 What is the risk of coupling a stainless steel spring or clip onto an aluminum chassis ?
Stainless steel possesses a noble cathodic potential (-50 mV) whereas structural aluminum is strongly anodic (-820 mV). In humid or saline environments, the potential delta exceeding 700 mV triggers severe localized pitting of the aluminum. If a small spring clip is mounted onto a large aluminum plate, the current density is diluted; conversely, a small aluminum part coupled to massive stainless steel suffers rapid structural perforation. Filame eliminates this risk with Zinc-Nickel or dielectric isolation.
03 What surface treatments does Filame provide for harsh salt spray environments ?
To safeguard stamped components and precision springs, Filame offers high-performance coatings: Zinc-Nickel (12-15% Ni, capable of achieving up to >1,000 hours in neutral salt spray testing per ISO 9227 depending on thickness and passivation), non-embrittling zinc flake coatings (Geomet/Dacromet per ISO 10683), pure electrolytic tinning for electrical contacts, and chemical passivation for stainless steels.
04 Can Filame manufacture production series meeting aerospace or automotive standards ?
Yes. Filame operates under ISO 9001 quality management and aligns with IATF 16949 and EN 9100 customer requirements. We manufacture medium to high volume runs on automatic high-speed presses up to 320 tonnes and Bihler multi-slide machines, providing EN 10204 3.1 material certificates, automated optical inspection (AOI) reports, and PPAP Level 3 documentation.
05 How can we submit 3D STEP drawings for engineering validation and an industrial quote ?
You can upload your CAD/STEP files or 2D technical drawings directly via our quote request form. Our engineering team reviews geometric tolerances, galvanic corrosion risks, and provides a clear manufacturing proposal.
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